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Titanium Silicalite-1 (TS-1)

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SKU# 147

Microporous Ti-Si Molecular Sieve, TS-1

Product Detail

ACS Material Titanium Silicalite-1 (TS-1) is a microporous Ti-Si molecular sieve supplied as a powder in the H+ form, with a SiO2/TiO2 molar ratio of ≥25, a BET surface area of 360–420 m²/g and a pore diameter of ~0.5 nm. It is calcined and ready to use directly.

Key specifications at a glance
SiO2/TiO2 molar ratio≥25
BET surface area360–420 m²/g
Pore diameter~0.5 nm
Comparative crystallinity>95%
Na2O<0.1%
CationH+

Overview

Titanium Silicalite-1, TS-1, was the first framework-substituted redox molecular sieve to be identified. Redox molecular sieves offer a significant advantage over standard heterogeneous catalysts; a redox sieve makes it possible to get a significantly higher selectivity to primary oxidation products. TS-1 has unique properties as a heterogeneous catalyst when H2O2 is used as the oxidant and H2O2 is attractive for industrial applications because of its relatively low cost and because it is clean.

ACS Material TS-1 is prepared using the hydrothermal method. Powder (Type B), 20–50 µm, is currently available; Powder (Type A), 0.3–0.5 µm, has been discontinued, and its specifications are kept on this page for reference.

Product information

ParameterValue
Product nameTitanium Silicalite-1 (TS-1); Microporous Ti-Si Molecular Sieve TS-1
CAS No.13463-67-7 (Titanium Dioxide) / 7631-86-9 (Silicon Dioxide)
Preparation methodHydrothermal Method
CationH+
SuppliedCalcined, ready to use directly

Characterizations

CharacterizationPowder (Type A) (Discontinued)Powder (Type B)
FormPowderPowder
SiO2/TiO2 molar ratio≥25≥25
Particle size (µm)0.3–0.520–50
Pore diameter (nm)~0.5~0.5
Pore volume (cm³/g)N/A~0.2
BET surface area (m²/g)360–420360–420
Comparative crystallinity (%)>95>95
Na2O (%)<0.1<0.1
CationH+H+

This product is calcined and ready to use directly. Powder (Type A) has been discontinued; its specifications are kept here for reference.

Ordering information

TypePackageProduct No.
Powder (Type B)50 gMSTS1B51
Powder (Type B)200 gMSTS2022
Powder (Type B)1 kgMSTS1B31

Typical data

Powder (Type B)

Typical SEM image of ACS Material TS-1 (Type B)
Typical XRD analysis of ACS Material TS-1 (Type B)
ACS Material TS-1, Type B: Left: typical SEM image (×1.50k; scale bar 30.0 µm); Right: typical XRD analysis (2θ 10–80°).

Application fields

Titano silicalite TS-1 has attracted attention due to its excellent catalytic properties in partial oxidation of many organic compounds, including:

  • Alkene epoxidation.
  • Cyclohexanone ammoxidation.
  • Alcohol oxidation.
  • Oxidation of saturated hydrocarbons.
  • Hydroxylation of aromatic hydrocarbons.

FAQ

What is the source of H+ in Powder (Type A) of TS-1?

H+ comes from an organic amine contained in the raw material. Powder (Type A) has been discontinued.

Does TS-1 need to be calcined before use?

No. ACS Material TS-1 is calcined and ready to use directly.

Which type and package sizes are available?

Powder (Type B), 20–50 µm, in 50 g (MSTS1B51), 200 g (MSTS2022) and 1 kg (MSTS1B31).

Where can I find the TDS and SDS?

The Technical Data Sheet (TDS) and Safety Data Sheet (SDS) for this product are available under the price on this page.

Published research using ACS Material TS-1

Disclaimer: ACS Material, LLC believes the information on this page is accurate and represents the best and most current information available to us. Specifications reflect the current published data; properties such as surface area and pore size may vary between batches — always refer to the product TDS for confirmed product-specific specifications, and follow your laboratory’s safety procedures for handling fine powders and solvents. ACS Material makes no representations or warranties, express or implied, regarding suitability for any purpose, and will not be responsible for damages resulting from use of or reliance upon this information.