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Covalent Organic Framework-DAAQ-TFP (DAAQ-TFP-COF)

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SKU# MC3

Product Detail

CAS-No.: 1477485-46-3

1. Preparation Method

Solvothermal synthesis 

DAAQ_TFP_COF_Flowchart2. Characterizations

Form:

Powder crystal

A two-dimensional planar material with one-dimensional channels

Solubility:

Insoluble in water or common organic solvents (N,N-dimethylformamide, tetrahydrofuran, dimethyl sulfoxide, acetone, trichloromethane)

Stability (Tg):

400 oC

BET Surface Area:

~365 m2/g

Pore Size:

1.9-2.3 nm

 FT-IR Spectra of ACS Material DAAQ-TFP-COF (red),  TFP monomer TFP (blue), DAAQ monomer  (black)

FT-IR Spectra of ACS Material DAAQ-TFP-COF (red), TFP monomer TFP (blue), DAAQ monomer  (black)

 SsNMR Spectra of ACS Material DAAQ-TFP-COF

SsNMR Spectra of ACS Material DAAQ-TFP-COF

PXRD pattern of ACS Material DAAQ-TFP-COF under dioxane growth conditions (red)  stacked with monomer 1 (black) and the model of P6/m (eclipsed) DAAQ-TFP-COF (blue).

PXRD pattern of ACS Material DAAQ-TFP-COF under dioxane growth conditions (red) stacked with monomer 1 (black) and the model of P6/m (eclipsed) DAAQ-TFP-COF (blue).

Adsorption isotherm for ground (20 min) ACS Material DAAQ-TFP-COF

Adsorption isotherm for ground (20 min) ACS Material DAAQ-TFP-COF

 BET surface area plot for ground (20 min) ACS Material DAAQ-TFP-COF

BET surface area plot for ground (20 min) ACS Material DAAQ-TFP-COF

Thermogravimetric trace of ACS Material DAAQ-TFP-COF 

Thermogravimetric trace of ACS Material DAAQ-TFP-COF

 Cyclic volatammogram before (red) and after (blue) holding the DAAQ-TFP-COF  at a reducing potential of -0.3 V for 24 h

Cyclic volatammogram before (red) and after (blue) holding the DAAQ-TFP-COF at a reducing potential of -0.3 V for 24h

3. Application Fields

1)     Batteries

2)     Supercapacitors

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