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Covalent Organic Framework-DAAQ-TFP (DAAQ-TFP-COF)

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SKU# MC3

Product Detail

CAS-No.: 1477485-46-3

1. Preparation Method

Solvothermal synthesis 

DAAQ_TFP_COF_Flowchart2. Characterizations

Form:

Powder crystal

A two-dimensional planar material with one-dimensional channels

Solubility:

Insoluble in water or common organic solvents (N,N-dimethylformamide, tetrahydrofuran, dimethyl sulfoxide, acetone, trichloromethane)

Stability (Tg):

400 oC

BET Surface Area:

~365 m2/g

Pore Size:

1.9-2.3 nm

 FT-IR Spectra of ACS Material DAAQ-TFP-COF (red),  TFP monomer TFP (blue), DAAQ monomer  (black)

FT-IR Spectra of ACS Material DAAQ-TFP-COF (red), TFP monomer TFP (blue), DAAQ monomer  (black)

 SsNMR Spectra of ACS Material DAAQ-TFP-COF

SsNMR Spectra of ACS Material DAAQ-TFP-COF

PXRD pattern of ACS Material DAAQ-TFP-COF under dioxane growth conditions (red)  stacked with monomer 1 (black) and the model of P6/m (eclipsed) DAAQ-TFP-COF (blue).

PXRD pattern of ACS Material DAAQ-TFP-COF under dioxane growth conditions (red) stacked with monomer 1 (black) and the model of P6/m (eclipsed) DAAQ-TFP-COF (blue).

Adsorption isotherm for ground (20 min) ACS Material DAAQ-TFP-COF

Adsorption isotherm for ground (20 min) ACS Material DAAQ-TFP-COF

 BET surface area plot for ground (20 min) ACS Material DAAQ-TFP-COF

BET surface area plot for ground (20 min) ACS Material DAAQ-TFP-COF

Thermogravimetric trace of ACS Material DAAQ-TFP-COF 

Thermogravimetric trace of ACS Material DAAQ-TFP-COF

 Cyclic volatammogram before (red) and after (blue) holding the DAAQ-TFP-COF  at a reducing potential of -0.3 V for 24 h

Cyclic volatammogram before (red) and after (blue) holding the DAAQ-TFP-COF at a reducing potential of -0.3 V for 24h

3. Application Fields

1)     Batteries

2)     Supercapacitors

Disclaimer: ACS Material, LLC believes that the information in this Technical Data Sheet is accurate and represents the best and most current information available to us. ACS Material makes no representations or warranties either express or implied, regarding the suitability of the material for any purpose or the accuracy of the information contained within this document. Accordingly, ACS Material will not be responsible for damages resulting from use of or reliance upon this information.