Covalent Organic Framework-DAAQ-TFP (DAAQ-TFP-COF)

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Product Detail

ACS Material Covalent Organic Framework-DAAQ-TFP (DAAQ-TFP-COF) is a covalent organic framework made by solvothermal synthesis and supplied as a powder crystal: a two-dimensional planar material with one-dimensional channels. It has a BET surface area of ~365 m²/g and a pore size of 1.9–2.3 nm, is insoluble in water and common organic solvents, and is used in batteries and supercapacitors.

Key specifications at a glance

Material classCovalent organic framework (COF)

Structure2D planar material, 1D channels

BET surface area~365 m²/g

Pore size1.9–2.3 nm

Stability (Tg)400 °C

Package100 mg

Product information

Parameter	Value
Product name	Covalent Organic Framework-DAAQ-TFP (DAAQ-TFP-COF)
Material class	Covalent organic framework (COF)
CAS No.	1477485-46-3
Preparation method	Solvothermal synthesis

Preparation scheme of ACS Material DAAQ-TFP-COF from TFP and DAAQ (solvothermal synthesis).

Characterizations

Characterizations	DAAQ-TFP-COF
Form	Powder crystal; a two-dimensional planar material with one-dimensional channels
Solubility	Insoluble in water or common organic solvents (N,N-dimethylformamide, tetrahydrofuran, dimethyl sulfoxide, acetone, trichloromethane)
Stability (Tg)	400 °C
BET surface area	~365 m²/g
Pore size	1.9–2.3 nm

Ordering information

Product	Type	Package	Product No.
DAAQ-TFP-COF	Type A	100 mg	MC3A00N1

Typical data

**Left:** FT-IR spectra of ACS Material DAAQ-TFP-COF, TFP monomer and DAAQ monomer; **Right:** solid-state ¹³C NMR spectrum of ACS Material DAAQ-TFP-COF.

Solid-state NMR spectrum of ACS Material DAAQ-TFP-COF — **Left:** FT-IR spectra of ACS Material DAAQ-TFP-COF, TFP monomer and DAAQ monomer; **Right:** solid-state ¹³C NMR spectrum of ACS Material DAAQ-TFP-COF.

**Left:** PXRD pattern of ACS Material DAAQ-TFP-COF under dioxane growth conditions (red), stacked with monomer 1 (black) and the model of P6/m (eclipsed) DAAQ-TFP-COF (blue); **Middle:** adsorption isotherm for ground (20 min) ACS Material DAAQ-TFP-COF; **Right:** BET surface area plot for ground (20 min) ACS Material DAAQ-TFP-COF.

Adsorption isotherm of ground ACS Material DAAQ-TFP-COF — **Left:** PXRD pattern of ACS Material DAAQ-TFP-COF under dioxane growth conditions (red), stacked with monomer 1 (black) and the model of P6/m (eclipsed) DAAQ-TFP-COF (blue); **Middle:** adsorption isotherm for ground (20 min) ACS Material DAAQ-TFP-COF; **Right:** BET surface area plot for ground (20 min) ACS Material DAAQ-TFP-COF.

Thermogravimetric trace of ACS Material DAAQ-TFP-COF — **Left:** thermogravimetric trace of ACS Material DAAQ-TFP-COF; **Right:** cyclic voltammogram before (red) and after (blue) the DAAQ-TFP-COF was kept at a reducing potential of −0.3 V for 24 h.

Cyclic voltammogram of ACS Material DAAQ-TFP-COF — **Left:** thermogravimetric trace of ACS Material DAAQ-TFP-COF; **Right:** cyclic voltammogram before (red) and after (blue) the DAAQ-TFP-COF was kept at a reducing potential of −0.3 V for 24 h.

Application fields

Batteries
Supercapacitors

FAQ

What are the BET surface area and pore size of DAAQ-TFP-COF?

The BET surface area is ~365 m²/g and the pore size is 1.9–2.3 nm.

How is DAAQ-TFP-COF made?

By solvothermal synthesis.

What is DAAQ-TFP-COF used for?

Batteries and supercapacitors.

Which package size is available?

100 mg, Type A (MC3A00N1).

Where can I find the TDS and SDS?

The Technical Data Sheet (TDS) and Safety Data Sheet (SDS) for this product are available under the price on this page.

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Disclaimer: ACS Material, LLC believes the information on this page is accurate and represents the best and most current information available to us. Specifications reflect the current published data; properties such as surface area and pore size may vary between batches — always refer to the product TDS for confirmed product-specific specifications, and follow your laboratory’s safety procedures for handling fine powders and solvents. ACS Material makes no representations or warranties, express or implied, regarding suitability for any purpose, and will not be responsible for damages resulting from use of or reliance upon this information.