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Covalent Organic Framework-TpPa-1 (COF-TpPa-1)

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Product Detail

CAS-No.: 1414350-37-0

1. Preparation Method

 Synthesized at room temperature and ambient atmosphere

2. Characterizations

Form:

Powder crystal

A two-dimensional planar material with one-dimensional channels

Solubility:

Insoluble in water or common organic solvents (N,N-dimethylformamide, tetrahydrofuran, dimethyl sulfoxide, acetone, trichloromethane)

Stability (Tg):

300-540 oC

BET Surface Area:

~1360 m2/g

Pore Size:

1.5-1.8 nm (depending on the R-group, the pore size varies slightly)

R-group:

-CH3/-NO2/H

  Typical SEM Image (1) of ACS Material COF-TpPa-1

Typical SEM Image of ACS Material COF-TpPa-1

FT-IR Spectra of ACS Material COF-TpPa-1 (red), 1,3,5-triformylbenzene 

FT-IR Spectra of ACS Material COF-TpPa-1 (red), 1,3,5-triformylbenzene

 SsNMR Spectra of ACS Material COF-TpPa-1

SsNMR Spectra of ACS Material COF-TpPa-1

 PXRD pattern of As-synthesized ACS Material COF-TpPa-1 (Blue)  compared with the Eclipsed (Black) and staggered (Red) stacking models.

PXRD pattern of As-synthesized ACS Material COF-TpPa-1 (Blue) compared with the Eclipsed (Black) and staggered (Red) stacking models.

 N2 adsorption (filled symbols) and desorption (empty symbols) isotherms  of ACS Material COF-TpPa-1

N2 adsorption (filled symbols) and desorption (empty symbols) isotherms of ACS Material COF-TpPa-1

 BET surface area plot for ACS Material COF-TpPa-1 calculated from the isotherm 

BET surface area plot for ACS Material COF-TpPa-1 calculated from the isotherm

Pore size distribution of ACS Material COF-TpPa-1

Pore size distribution of ACS Material COF-TpPa-1

 TGA data of activated COF TpPa-1 under N2 atmosphere

TGA data of activated COF TpPa-1 under N2 atmosphere

3. Application Fields

1)     Metal Coordination Catalysis

2)     Recognition of metal ions

3)     Bio-Detection

4)     Chiral separation

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